سنتز و بررسی خواص جذب فریت کبالت و نانوکامپوزیت فریت کبالت-هیدروکسی آپاتیت

نوربخش, حمید; حسن زاده تبریزی, سید علی

doi:10.22076/me.2020.115920.1264

سنتز و بررسی خواص جذب فریت کبالت و نانوکامپوزیت فریت کبالت-هیدروکسی آپاتیت

نوع مقاله : مقاله پژوهشی

نویسندگان

¹ دانشجوی کارشناسی ارشد، مرکز تحقیقات مواد پیشرفته، دانشکده مهندسی مواد، واحد نجف آباد، دانشگاه آزاد اسلامی، نجف‌آباد، ایران.

² دانشیار، مرکز تحقیقات مواد پیشرفته، دانشکده مهندسی مواد، واحد نجف آباد، دانشگاه آزاد اسلامی، نجف‌آباد، ایران.

10.22076/me.2020.115920.1264

چکیده

در این تحقیق، پودر فریت کبالت (CoFe2O4) و کامپوزیت فریت کبالت-هیدروکسی آپاتیت به روش هم رسوبی سه مرحله‌ای سنتز شد. پودرهای سنتز شده با استفاده از روش‌های مشخصه‌‌یابی پراش پرتو ایکس (XRD)، میکروسکوپ الکترونی روبشی گسیل میدانی (FESEM) و طیف سنجی مادون قرمز (FTIR) مشخصه‌یابی شدند. نتایج پراش پرتو ایکس تشکیل فاز هیدروکسی آپاتیت در کنار پیک‌های فریت کبالت را تایید می‌کند. طیف FTIR نشان دهنده تشکیل پیوند‌های فسفاتی در ترکیب بود که تایید کننده تشکیل هیدروکسی آپاتیت در کنار فاز فریت کبالت بود. نتایج آزمایشات جذب رنگ متیلن بلو ذرات نانو کامپوزیتی سنتز شده نشان داد با افزایش pH مقدار جذب رنگ افزایش داشت. همچنین مقادیر بهینه جذب با استفاده از 03/0 گرم از جاذب در غلظت 10 میلی گرم بر لیتر از متیلن بلو و 9=pH در زمان 45 دقیقه در حدود 100 درصد به دست آمد. همچنین در نتایج به دست آمده مشاهده شد که میزان جذب متیلن بلو بر روی کامپوزیت سنتز شده بسیار بالاتر از فریت کبالت بود و نیز نسبت به هیدروکسی آپاتیت خالص در زمان پایین‌تری جذب انجام گرفت.

کلیدواژه‌ها

20.1001.1.15631745.1398.22.4.6.0

عنوان مقاله [English]

Synthesis and adsorption properties of cobalt ferrite and cobalt ferrite-hydroxyapatite nanocomposite

نویسندگان [English]

Hamid Nourbakhsh ¹
Ali Hassanzadeh-Tabrizi ²

¹ MSc student, Advanced Materials Research Center, Department of Materials Engineering, Najafabad Branch, Islamic Azad University, Najafabad, Iran.

² Associate Professor, Advanced Materials Research Center, Department of Materials Engineering, Najafabad Branch, Islamic Azad University, Najafabad, Iran.

چکیده [English]

In this study, cobalt ferrite powder (CoFe2O4) and cobalt ferrite-hydroxyapatite composite were synthesized by three-step co-deposition method. The synthesized powders were characterized by X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM) and infrared spectroscopy (FTIR) techniques. The XRD results confirm the formation of the hydroxyapatite phase along the cobalt ferrite peaks. The FTIR spectra showed the formation of phosphate bonds in the compound, confirming the formation of hydroxyapatite along the cobalt ferrite phase. The results of the dye adsorption experiments on the synthesized nanocomposite methylene blue showed that with increasing pH the amount of dye adsorption increased. Also, optimum adsorption values were obtained using 0.03 g of adsorbent at concentration of 10 mg/L of methylene blue and pH=9 at about 100% for 45 min. The results also showed that the adsorption of methylene blue on the synthesized composite was much higher than that of cobalt ferrite and also at lower adsorption time than pure hydroxyapatite.

کلیدواژه‌ها [English]

Cobalt Ferrite
Hydroxyapatite
Composite
Color Adsorption
Methylene Blue

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