بررسی سینتیک تبلور شیشه فلز حجیم Au50Cu25.5Ag7.5Si17 تحت گرمایش پیوسته و هم دما

رحیمی چگنی, مریم; نیلی احمدآبادی, محمود; ملکان, مهدی

doi:10.22076/me.2019.85583.1190

بررسی سینتیک تبلور شیشه فلز حجیم Au50Cu25.5Ag7.5Si17 تحت گرمایش پیوسته و هم دما

نوع مقاله : مقاله پژوهشی

نویسندگان

دانشکده مهندسی متالورژی و مواد دانشگاه تهران

10.22076/me.2019.85583.1190

چکیده

در پژوهش حاضر رفتار سینتیکی فلز شیشه‌ای حجیم پایه طلا با ترکیب Au50Cu25.5Ag7.5Si17 (at%) در محدوده مذاب فوق تبرید شده مورد بررسی قرار گرفت. سینتیک استحاله شیشه‌ای شدن و تبلور این آلیاژ شیشه‌ای تحت شرایط گرمایش پیوسته ( غیر هم‌دما) و هم‌دما توسط گرماسنجی روبشی افتراقی بررسی شد. نتایج حاکی از وقوع تبلور یک مرحله‌ای در آلیاژ طی گرمایش پیوسته است. نتایج نشان داد که دمای تبلور و شیشه‌ای شدن تابعی از نرخ گرمایش هستند. تحت شرایط غیر هم‌دما، انرژی‌های اکتیواسیون مرتبط با دماهای مشخصه توسط رابطه کیسینجر محاسبه شدند. . مقدار انرژی اکتیواسیون برای هر یک از استحاله‌های تحول شیشه، تبلور و پیک تبلور به ترتیب 246، 183 و 161 kJ/mol به دست آمده است. مقادیر انرژی‌های اکتیواسیون محاسبه شده حاکی از بیشتر بودن انرژی لازم برای تحول شیشه نسبت به تبلور است. مکانیسم تبلور تحت شرایط هم‌دما توسط رابطه جانسون – مل – اورامی بررسی شد. مقدار توان اورامی در بازه 1 تا 6/1 محاسبه شد که نشان دهنده جوانه‌زنی ناهمگن ذرات با حجم قابل توجه در آغاز تحول می‌باشد.

کلیدواژه‌ها

20.1001.1.15631745.1398.22.1.1.9

عنوان مقاله [English]

Crystallization Kinetics Of Au50Cu25.5Ag7.5Si17 Bulk Metallic Glass Under Continuous and Isothermal Heating

نویسندگان [English]

Maryam Rahimi-Chegeni
Mahmoud Nili-Ahmadabadi
Mahdi Malekan

School of Metallurgy and Materials Engineering, University of Tehran

چکیده [English]

In this study, the kinetic of Au-based BMG (Au50Cu25.5Ag7.5Si17 (at%)) at high temperature in supercooled liquid region was investigated Crystallization kinetics of this amorphous alloy under non-isothermal (continuous heating) and isothermal conditions were investigated by differential scanning calorimetry (DSC). The results show that crystallization in this bulk metallic glass has one stage crystalline precipitation process during continuous heating. It was found that glass transition and crystallization kinetics are the function of continuous heating rate. Under non-isothermal conditions, activation energies corresponding to the characteristic temperatures were estimated by Kissinger equation. The calculated activation energies of glass transition, onset of crystallization and crystallization peak temperature are 246,183 and 161 kJ/mol respectively. These activation energies revealed that the energy barrier for the glass transformation is higher than that for crystallization. The crystallization mechanism under isothermal condition was investigated by using Johnson – Mehl – Avrami (JMA) equation. The Avrami exponent is mainly in the range of 1 to 1.6, which indicates heterogeneous nucleation with significant volume at the beginning of the transformation.

کلیدواژه‌ها [English]

Bulk Metallic Glass
Crystallization kinetics
Activation energy
Kissinger method
Johnson – Mehl – Avrami method

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