Metallurgical Engineering

Metallurgical Engineering

Synthesis of Fe-TiC composite coating on plain carbon steel surface to hardness increasing by using laser alloying process

Document Type : Research Paper

Authors
Abstract
In this research synthesis and creating of Fe-TiC coating on plain carbon steel using ilmenite and laser alloying process was investigated. Two composition with the molar ratio of graphite to ilmenite 4:1 and 6:1 was investigated. The sample with molar ratio 6:1, were activated for 100h. Blended powder were mixed with amount of glue and pasted on AISI 1018 surface. Then laser surface alloying was done. The Result showed in un-milled sample ilmenite not reduction to TiC but in activated sample ilmenite reduction to Fe and TiC. The results showed that TiC were formed via in situ reaction between ilmenite and graphite in the molten pool during laser alloying process. The morphologies of TiC were of spherical shape; and the titanium carbides were distributed uniformly in the composite coating. Compared to the substrate, the hardness of the coatings reinforced by TiC particles were significantly enhanced.
Keywords

 
1-       Ariely, S., J. Shen, M. Bamberger, F. Dausiger and H. Hugel (1991). "Laser surface alloying of steel with TiC." Surface and Coatings Technology 45(1): 403-408.
2-       Asthana, R., A. Kumar and N. B. Dahotre (2006). Materials processing and manufacturing science, Butterworth-Heinemann.
3-       Burakowski, T. and T. Wierzchon (1998). Surface engineering of metals: principles, equipment, technologies, CRC press.
4-       Calka, A., D. Oleszak and N. Stanford (2008). "Rapid synthesis of TiC–Fe< sub> 3 C composite by electric discharge assisted mechanical milling of ilmenite (FeTiO< sub> 3) with graphite." Journal of alloys and compounds 459(1): 498-500.
5-       Chehrghani, A., M. Torkamany, M. Hamedi and J. Sabbaghzadeh (2012). "Numerical modeling and experimental investigation of TiC formation on titanium surface pre-coated by graphite under pulsed laser irradiation." Applied Surface Science 258(6): 2068-2076.
6-       Chen, Y., T. Hwang, M. Marsh and J. Williams (1997). "Mechanically activated carbothermic reduction of ilmenite." Metallurgical and Materials Transactions A 28(5): 1115-1121.
7-       Das, K., T. Bandyopadhyay and S. Das (2002). "A review on the various synthesis routes of TiC reinforced ferrous based composites." Journal of materials science 37(18): 3881-3892.
8-       Dewan, M. A., G. Zhang and O. Ostrovski (2010). "Carbothermal reduction of a primary ilmenite افشرده in different gas atmospheres." Metallurgical and Materials Transactions B 41(1): 182-192.
9-       Emamian, A., S. F. Corbin and A. Khajepour (2011). "The influence of combined laser parameters on in-situ formed TiC morphology during laser cladding." Surface and Coatings Technology 206(1): 124-131.
10-   Jiang, W. and R. Kovacevic (2007). "Laser deposited TiC/H13 tool steel composite coatings and their erosion resistance." Journal ofmaterials processing technology 186(1): 331-338.
11-   Raghavan, V. (2003). "C-Fe-Ti (carbon-iron-titanium)." Journal of phase equilibria 24(1): 62-66.
12-   Toyserkani, E., A. Khajepour and S. F. Corbin (2004). Laser cladding, CRC press.
13-   Welham, N. (1998). "Mechanically induced reduction of ilmenite (FeTiO< sub> 3) and rutile (TiO< sub> 2) by magnesium." Journal of alloys and compounds 274(1): 260-265.
14-   Welham, N. and P. Willis (1998). "Formation of TiN/TiC-Fe composites from ilmenite (FeTiO3) concentrate." Metallurgical and Materials Transactions B 29(5): 1077-1083.
15-   William, M. S. (1991). Laser material processing, Springer-Verlag, Berlin.
16-   Wu, X. (1999). "In situ formation by laser cladding of a TiC composite coating with a gradient distribution." Surface and Coatings Technology 115(2): 111-115.
17-   Xiaolei Wu, Y. H. (2001). "Microstructure and mechanical properties at TiCp/Ni-alloy interfaces in laser-synthesized coatings."
18-   Yang, S., M. Zhong and W. Liu (2003). "TiC particulate composite coating produced in situ by laser cladding." Materials Science and Engineering: A 343(1): 57-62.